On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.
| Autoři | |
|---|---|
| Rok publikování | 2001 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Polyhedron |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | four-membered heterocycle; five-membered heterocycle; diazadiphosphetidine; chlorodithiophosphoric acid pyridiniumbetaine |
| Popis | Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography. |
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