Synthesis and Chemical Properties of Halogenophosphates
Autoři | |
---|---|
Rok publikování | 2002 |
Druh | Článek ve sborníku |
Konference | Sborník příspěvků IV. seminář Pokroky v anorganické chemii |
Fakulta / Pracoviště MU | |
Citace | |
Obor | Anorganická chemie |
Klíčová slova | Diphosphoryl tetrafluoride; dichlorophosphate; chlorofluorophosphate; 1;1-difluoro-2-chlorodiphosphate; 1;1;2-trifluorodiphosphate; 1;1;3;3-tetrafluorotriphosphate |
Popis | The systematic study of the synthetic methods and structures of halogenophosphates enabled the succesfull preparations of tetraphenylphosphonium dichlorophosphate and 1,1,3,3-tetrafluorotriphosphate,which constitution was confirmed by X-ray crystal structure analysis.In addition,also the pure solid PPh4[PO2ClF] was isolated and the formation of 1,1,2-trifluorodiphosphate and 1,1,-difluoro-2-chlorodiphosphate could be revealed by 19F and 31P NMR spectroscopy. |
Související projekty: |