Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

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Publikace nespadá pod Pedagogickou fakultu, ale pod Přírodovědeckou fakultu. Oficiální stránka publikace je na webu muni.cz.
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BARTOŠ Petr MAZAL Ctibor

Rok publikování 2004
Druh Článek ve sborníku
Konference Chemické listy, IV. Mezioborové setkání mladých biologů,
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
Obor Organická chemie
Klíčová slova bicyclopentanes; staffanes; cyclodextrin; pseudorotaxanes; NMR
Popis Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of [1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemistry of BCPs.
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