Separation of Trinitrotoluenes and Product of their Biotransformation by Capillary Electrophoresis and Liquid Chromatography

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Publikace nespadá pod Pedagogickou fakultu, ale pod Přírodovědeckou fakultu. Oficiální stránka publikace je na webu muni.cz.
Název česky Separace trinitrotoluenů a produktů jejich biotransformace kapilární elektrofirézou a kapalinovou chromatografií
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BEČANOVÁ Jitka ŠIMEK Zdeněk HERNÍKOVÁ Věra

Rok publikování 2005
Druh Článek ve sborníku
Konference Abstract Book- 29th International Symposium on High Performance Liquid Phase Separations and Related Techniques
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
Obor Analytická chemie, separace
Klíčová slova Trinitrotoluenes; Capillary Electrophoresis; Liquid Chromatography
Popis Nitroderivatives of toluene such as trinitrotoluenes and products of their biotranformations, aminodinitrotoluenes (ADNT) and diaminonitrotoluenes (DANT) are widely distributed in the environment. These compounds have been found as contaminants in soils at munitions manufacturing facilities, storage depots, and sites of the explosives use. They have mutagenic, carcinogenic and toxic effects [1]. Comparison of retention behaviour of selected nitroderivatives of toluene and aminonitroderivatives of toluene in liquid chromatography (HPLC), capillary electrochromatography (CEC) and micellar electrokinetic chromatography (MECC) separation systems is presented. Effect of pH, concentration of background electrolyte, sodium dodecylsulphate and organic modifier concentration both in electrolyte and mobile phase was investigated. Different gradient elution in reversed phase liquid chromatography system was studied. The applicability of used separation method for determination of toluene nitroderivatives in environmental samples is discussed.
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