Study of dehalogenation of halogenoanilines using Raney Al-Ni alloy in aqueous medium at room temperature

Varování

Publikace nespadá pod Pedagogickou fakultu, ale pod Přírodovědeckou fakultu. Oficiální stránka publikace je na webu muni.cz.

Autoři	WEIDLICH Tomáš KREJČOVÁ Anna PROKEŠ Lubomír
Rok publikování	2010
Druh	Článek v odborném periodiku
Časopis / Zdroj	Monatshefte fuer Chemie, Chemical Monthly
Fakulta / Pracoviště MU	Přírodovědecká fakulta
Citace
www	http://www.springerlink.com/content/e21013535k7mrjl1/
Obor	Organická chemie
Klíčová slova	Reductions - AOX removal - NMR spectroscopy - Metals - ICP-OES
Popis	Dehalogenation of halogenated anilines by action of powdered aluminium-nickel alloy in aqueous alkaline solution at room temperature has been studied. The reaction course was monitored by means of 1H nuclear magnetic resonance (NMR) spectroscopy. The rates of dehalogenation of 4-bromo-, 4-chloro-, 4-fluoro- and 3-chloroaniline were compared under conditions of minimum necessary excess of Al-Ni alloy as reducing agent in edetane buffer medium at pH 10.9. On the basis of the results obtained in buffers, the dehalogenation method of aqueous solutions of halogenoanilines was verified using NaOH as the base.