Determination of atrazine in surface waters by combination of POCIS passive sampling and ELISA detection.
| Autoři | |
|---|---|
| Rok publikování | 2011 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Journal of Environmental Monitoring |
| Fakulta / Pracoviště MU | |
| Citace | |
| Doi | http://dx.doi.org/10.1039/c1em10112a |
| Obor | Vliv životního prostředí na zdraví |
| Klíčová slova | SEMIPERMEABLE-MEMBRANE DEVICES; CHEMICAL INTEGRATIVE SAMPLERS; TANDEM MASS-SPECTROMETRY; SOLID-PHASE EXTRACTION; ORGANIC CONTAMINANTS; WASTE-WATER; AQUATIC ENVIRONMENTS; PHARMACEUTICALS; PESTICIDES; POLLUTANTS |
| Popis | In the present study, POCIS technology was applied to surface water sampling in the Czech Republic, and ELISA was used as a detection technique for the herbicide atrazine. In the first study, 28 samples from streams around small municipal waste water treatment plants (WWTPs) were collected using two different devices (POCISpest and POCISpharm) over the course of 21 days. Elevated atrazine concentrations (up to 25 ng per POCIS) were found in samples down-stream of WWTPs. This observation was also confirmed in another two year study (4 sampling periods) investigating 7 river sites around a major city of Brno as well as the inlet and outlet of the city's WWTP. High atrazine levels were systematically determined at the outlet from the WWTPs (120-605 ng per POCIS). A decreasing trend in the atrazine concentrations with the highest levels observed within the first sampling period in spring 2007 (100-600 ng per POCIS, with an extreme value of 2760 ng per POCIS). Results of the ELISA were closely correlated with LC-MS/MS |
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