Diethyl [4-(2,2:6,2-terpyridine-4-yl)phenyl]phosphonate

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Authors	CHYBA Jan NEČAS Marek PINKAS Jiří
Year of publication	2013
Type	Article in Periodical
Magazine / Source	Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit	Central European Institute of Technology
Citation
web	http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885073/
Doi	http://dx.doi.org/10.1107/S1600536813031541
Field	Inorganic chemistry
Keywords	terpyridine; phosphonate; structure
Description	The title compound, C25H24N3O3P, was obtained by catalytic phosphonation of 4'-(4-bromphenyl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9) deg. The N atoms in the two pyridine rings are oriented nearly antiperiplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6) deg.
Related projects:	Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti CEITEC - Central European Institute of Technology