Detekce těkavých a částečně těkavých meziproduktů a produktů elektrochemických procesů hmotnostní spektrometrií

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Title in English Detection of volatile and semivolatile intermediates and poducts of electrochemical processes by means of mass spectrometry
Authors

DRBÁLKOVÁ Eva JANDERKA Pavel CHALOUPKOVÁ Radka

Year of publication 2000
Type Article in Proceedings
Conference Proceedens of the 18th Informal Meeting on Mass Spectrometry
MU Faculty or unit

Faculty of Science

Citation
Field Electrochemistry
Keywords DEMS mass spectrometry electrochemistry aromatic hydrocarbons adsorption
Description The presentation describes possible on-line connection of electrochemical cell and mass spectrometer, used for detection, identification and observation in time of volatile and semivolatile species during electrochemical polarisation of working electrode. As a trial system we studied the process of electrochemical hydrogenation of naphthalene and benzene in 0.5M sulphuric acid on polycristalline Pt electrode. Beside the hydrogenated products the parent hydrocarbons after desorption were detected.
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