Laser ablation synthesis of selenium superoxide anion SeO4- via selenium trioxide photolysis. Time-of-flight mass spectrometry and ab initio calculations

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Authors

ALBERTI Milan ŠPALT Zbyněk PEŇA-MÉNDEZ María Eladia RAMÍREZ-GALICIA Guillermo HAVEL Josef

Year of publication 2005
Type Article in Periodical
Magazine / Source Rapid Communications in Mass Spectrometry
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords Laser ablation synthesis; selenium superoxide; ab initio calculations
Description For the first time selenium superoxide SeO4 in the form anion SeO4- was detected by means LDI-TOF-MS. Ab initio calculation were performed to support the mass spectrometric evidence and peroxidic structure of the described compound also.
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