Preparation of 1-Adamantylketones: Structure, Mechanism of Formation and Biological Activity of Potential Byproducts

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Authors

VÍCHA Robert NEČAS Marek POTÁČEK Milan

Year of publication 2006
Type Article in Periodical
Magazine / Source Collection of Czechoslovak Chemical Communications
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords Collect. Czech. Chem. Commun. 2006; 71(5); 709-722.
Description Reactions between adamantane-1-carbonyl chloride and several Grignard reagents as well as interactions with solvents have been examined. Some new and unexpected adamantane derivatives were isolated, fully characterized and their biological activity determined. In particular, an unexpected isochromanone 16 was formed in an SEAr process where a stable hydrocarbon was the leaving group.
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