On the formation kinetics of two-dimensional cytidine films.
Autoři | |
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Rok publikování | 2002 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Bioelectrochemistry |
Fakulta / Pracoviště MU | |
Citace | |
Obor | Biofyzika |
Klíčová slova | two-dimensional condensation; cytidine adsorption; nucleation and growth; cytidine adlayers; |
Popis | The kinetics of phase transitions of cytidine adsorbed at the mercury electrode were studied by chronoamperometry and capacitance measurements. Cytidine forms highly ordered two-dimensional adlayers in a broad range of pH. The formation of the cytidine adlayer a compact film - is characterised by capacitance pits on C-E curves and current spikes on cyclic voltammograms. The interfacial transformation of the cytidine films yield a sigmoidal C-t transient which was analysed by Avrami theorem. |
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