Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle
| Authors | |
|---|---|
| Year of publication | 2017 |
| Type | Article in Periodical |
| Magazine / Source | Chemistry - A European Journal |
| MU Faculty or unit | |
| Citation | |
| Web | http://onlinelibrary.wiley.com/doi/10.1002/chem.201704948/abstract |
| Doi | http://dx.doi.org/10.1002/chem.201704948 |
| Field | Macromolecular chemistry |
| Keywords | anion recognition; bambusurils; controlled release; macrocycles; self-assembly |
| Description | The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex in water (log K-a = 6.9 M-1) by addition of a more strongly bound anion, such as iodide (log K-a = 7.1 M-1), which can also be delivered in situ upon irradiation from a 4-hydroxyphenacyl iodide derivative with spatial and temporal precision. The oxidizing properties of peroxodisulfate ions liberated from the complex recover and can take part in subsequent chemical transformations. |
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