Molecular Metal Alkoxide Phosphates

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Authors

CHYBA Jan MORAVEC Zdeněk NEČAS Marek MATHUR Sanjay PINKAS Jiří

Year of publication 2010
Type Article in Proceedings
Conference 1st Czech-French Vltava Meeting of Chemistry in Burgundy
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords aluminum; phosphates; alkoxides
Description We performed condensation reactions between selected derivates of phosphoric acid and metalloorganic compounds, such as metal alkyls and alkoxides, which provided molecular metallophosphates of different shapes and metal nuclearities. The X-ray diffraction analysis revealed inorganic cores wrapped in the organic coats formed by reactive functional groups. The prepared products were characterized by analytical and spectroscopic methods (NMR, IR, MS). Obtained analytical data expand structural platform of metallophosphate framework systems.
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